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課程名稱 |
無機化學一
INORGANIC CHEMISTRY(Ⅰ) |
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開課學期 |
95-1 |
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授課對象 |
理學院 化學系 |
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授課教師 |
王 瑜 |
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課號 |
Chem3023 |
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課程識別碼 |
203 34210 |
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班次 |
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學分 |
3 |
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全/半年 |
半年 |
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必/選修 |
必帶 |
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上課時間 |
星期一2(9:10~10:00)星期三3,4(10:20~12:10) |
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上課地點 |
化217教室普通503 |
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備註 |
1.先修：普通化學。2.詳選課須知。3.外系生需經教師同意。本課程中文
限學士班三年級以上 且 限本系所學生(含輔系、雙修生)
總人數上限：80人 |
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Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/951inorg_1 |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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為確保您我的權利,請尊重智慧財產權及不得非法影印
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課程概述 |
The course is designed for
students who have already
acquired the basic skills
in reading and writing
English, and who would like
to improve these skills so
as to be able to read essays
and books in English on a
broad range of
subjects, and make comments
on the writings they are
dealing with. |
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課程目標 |
The selections of readings
to be covered on the
syllabus are expected to
help
the class expand the volume
of vocabulary on subjects
which engage the
attention of average
students at the graduate
level. The readings are also
chosen as models of fluency
and eloquence. This means
that vocabulary, grammar
and style are acquisition
targets of the class. |
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課程要求 |
Students of the class are
expected to do before-class
preparations and all the
assignments given after
every class. There will be
writing tests for the mid-
term and the final. Also
there will be short writing
exercises to be done at
home. As the reading
materials will either be
uploaded to the class
webpage or
distributed to the
individual e-mail box, it is
expected that all students
have proper computing
equipments and essential
operating skills to get the
class work going. The class
are also expected to keep
close attention to the
announcements on the
bulletinboard to be well
informed of what-to-dos and
how-
to-dos for the course. |
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預期每週課後學習時數 |
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Office Hours |
另約時間 |
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指定閱讀 |
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參考書目 |
”Inorganic Chemistry” 3rd Edition；Gary L. Miessler、
Donald A. Tarr
”Inorganic Chemistry” 3rd Edition；D. F. Shriver、P. W.
Atkins；OXFORD |
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評量方式
(僅供參考) |
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週次 |
日期 |
單元主題 |
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第1週 |
9/18,9/20 |
1.無機化學簡介 Introduction to Inorganic Chemistry
週期表,化學結構與化學鍵(Periodic system, Structure and Bonding)
合成,反應與機構探討(Synthesis, Reaction and Mechanism)
2.原子結構 Atomic Structure
多電子之原子結構與週期表(Polyelectronic Atomic Structure and Periodic System)
罕得定律,奧福寶規則,電子雲遮蔽效應(Hund’s rule, Aufbau principle, nuclear shielding)
游離能,電子親和力,與電負度(Ionic energy, electronic affinity, and electronegativity)
項次符號與能階(Term symbol & energy state)
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第2週 |
9/25,9/27 |
2.原子結構 Atomic Structure
游離能,電子親和力,與電負度(Ionic energy, electronic affinity, and electronegativity)
項次符號與能階(Term symbol and energy state)
3.基本化學鍵結理論 Simple Bonding Theory
共價鍵(The Covalent Bond)
價鍵理論入門(Valence Bond approaches)
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第3週 |
10/02,10/04 |
3.基本化學鍵結理論 Simple Bonding Theory
混成與非定域化(Hybridization and delocalization)
分子形狀(Molecular Shape)
價殼電子對排斥理論(VSEPR)
實驗方法決定電荷分布(Experimental determination of Charge Distribution)
分子間作用力(Intermolecular forces)
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第4週 |
10/09,10/11 |
4.對稱與群論 Symmetry and Group Theory
對稱元素與對稱操作(Symmetry elements and symmetry operations)
對稱點群(Symmetry point groups)
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第5週 |
10/16,10/18 |
4.對稱與群論 Symmetry and Group Theory
級,表徵與徵表(Class, representations and character tables)
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第6週 |
10/23,10/25 |
4.對稱與群論 Symmetry and Group Theory
對稱性之化學應用(Chemical applications of symmetry)
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第7週 |
10/30,11/01 |
5.分子軌域 Molecular Orbitals
由s與p軌域形成分子軌域(Formation of molecular orbitals from s and p orbitals)
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第8週 |
11/06,11/08 |
5.分子軌域 Molecular Orbitals
同核雙原子分子(Homonuclear diatomic molecules)
異核雙原子分子(Heteronuclear diatomic molecules)
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第9週 |
11/13,11/15 |
5.分子軌域 Molecular Orbitals
多原子分子(Larger molecules)
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第10週 |
11/20,11/22 |
5.分子軌域 Molecular Orbitals
具p鍵之平面環狀分子(Cyclic-planar p molecules)
第一次考試 (1st Monthly Exam) Chapter 1.~4.
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第11週 |
11/27,11/29 |
5.分子軌域 Molecular Orbitals
由d軌域形成分子軌域(Molecules orbitals from d orbitals)
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第12週 |
12/04,12/06 |
6.酸與鹼 Acid-Base and Donor-Acceptor Chemistry
阿瑞尼茲理論與水溶液中之酸鹼(Arrehnius Theory and Acids/Bases in Aqueous Solutions)
布朗斯特-勞瑞理論(Bronsted-Lowry Theory)
共軛酸鹼對(Conjugated acid-base)
非水溶液系統 (Lux觀點) (Non-aqueous solution systems (Lux Concept))
含氧酸介紹(Descriptive - Oxoacids)
路易士酸鹼定義(Lewis Definition of Acid/Base)
軌域模型之描述(Definition and Orbital Model)
酸鹼說明(Descriptive)
親電子性與親質子性(Electron Affinity versus Proton affinity)
感應,共振,與立體效應(Inductive, resonance, and steric effects)
酸鹼之軟硬度(Hard-Soft Acid-Base)
硬度與軟度(Hardness and Softness)
種類與反應(Descriptive and Reactions)
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第13週 |
12/11,12/13 |
7.固態化學 The Crystalline Solid State
晶格結構(Crystal structure)
晶格,單位晶格,米勒指數,倒晶格(lattice, unit cell, Miller indices, reciprocal lattice)
缺陷結構(Defect Structure)
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第14週 |
12/18,12/20 |
7.固態化學 The Crystalline Solid State
史特基與伏蘭克缺陷,非化學計量之化合物(Schottky and Frenkel Defects, nonstoichiometric compounds)
第二次考試 (2nd Monthly Exam) Chapter 1.~6.
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第15週 |
12/25,12/27 |
7.固態化學 The Crystalline Solid State
金屬,絕緣體與半導體(Metals, Insulators and Semiconductors)
價帶,導電帶,鑲嵌,n-型,p-型(Valence band, conduction band, dopant, n-type, p-type)
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第16週 |
1/01,1/03 |
7.固態化學 The Crystalline Solid State
超導體(Superconductivity)
性質,結構,製程(Properties, structure, processing)
矽氧化物之結構,椅狀,環狀,簇狀與籠狀結構(Structures of Silicates, Chains, Rings, Cluster and Cage Compounds)
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第17週 |
1/08,1/10 |
8.主族化學元素 Chemistry of the Main Group Elements
氫與其化合物(Hydrogen and Compounds)
金屬氫化合物(Metallic Hydrides)
氫氣儲存(Hydrogen Storage)
s- & p-族元素(s- & p-Block Elements)
鹼金屬與鹼土金屬(Alkali and Alkali Earth Metals)
氮與磷(Nitrogen and Phosphorus)
氧,硫與硒(Oxygen, Sulfur and Selenium)
鹵素(The Halogens)
惰性氣體(The Nobel Gases)
d-族元素(d-Block Elements)
電子結構,氧化態與電動勢(Electron Configuration, Oxidation States and EMF)
配位化合物與有機金屬化合物(Coordination Compound and Organometallic Compounds)
f-族元素(f-Block Elements)
鑭系與錒系元素(The Lanthanide and Actinide)
電子結構,氧化態(Electron Configuration and Oxidation States)
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